IWO缓冲层对MOCVD-ZnO:B薄膜性能的影响研究
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TN304.055

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国家“973”重点基础研究(2011CBA00705,2011CBA00706,2011CBA00707);国家高技术研究发展计划(2009AA050602);科技部国际合作项目(2009DFA62580);天津市应用基础及前沿技术研究计划(09JCYBJC06900);中央高校基本科研业务费专项资金(65010341)资助项目


Influence of IWO buffer layer on the properties of MOCVD-ZnO:B thin films
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    摘要:

    金属有机化学气相沉积(MOCVD)技术生长的绒面ZnO透明导电(ZnO-TCO)薄膜应用于Si基薄膜太阳电池上能够形成"陷光结构",以提高薄膜太阳电池效率和稳定性。本文将电子束反应蒸发技术生长的掺W的In2O3(In2O3:W,(IWO)薄膜作为缓冲层,应用于MOCVD-ZnO:B薄膜与玻璃之间,可促进ZnO:B薄膜的生长,并且有效提升薄膜的光散射特性。当IWO缓冲层厚度为20nm时,获得的IWO/ZnO:B薄膜的电阻率为2.07×10-3Ω.cm,迁移率为20.9cm2.V-1.s-1,载流子浓度为1.44×1020 cm-3;同时,薄膜具有的透过率大于85%,且在550nm处绒度较ZnO:B薄膜提高了约9.5%,在800nm处绒度较ZnO:B薄膜提高了约4.5%。

    Abstract:

    Light trapping effect is formed when the textured ZnO:B-TCO thin films deposited by MOCVD technique are used in Si-based thin film solar cells,which is important for improving the short-circuit current and the stability of thin film solar cells.In this paper,In2O3:W(IWO) thin films deposited by electron beam evaporation were grown between the glass substrates and ZnO:B thin films as buffer layers,which can promote the growth of ZnO:B thin films.And the scattering characteristics of ZnO:B thin films are improved effectively.When the thickness of IWO thin film is 20 nm,bi-layer IWO/ZnO:B thin films with the resistivity of 2.07×10-3 Ω·cm,mobility of ~20.9 cm2·V-1·s-1 and carrier concentration of 1.44×1020 cm-3 are obtained.Meanwhile,these bi-layer thin films present high transparencies over 85%,and the haze of these thin films increases by about 9.5% at 500 nm wavelength and about 4.5% at 800 nm wavelength.

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闫聪博,陈新亮,陈雪莲,孙建,张德坤,魏长春,张晓丹,赵颖,耿新华. IWO缓冲层对MOCVD-ZnO:B薄膜性能的影响研究[J].光电子激光,2012,(4):697~702

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