ZnO多晶薄膜绒面结构及陷光特性分析
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黄茜(1982-),女,天津市人,博士,讲师,主要从事薄膜 太阳电池及新型光伏材料领域研究工作.

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国家重点基础研究发展计划(2011CBA00706)、国家高技术研究发展计划(2011AA050503)、教育部重点实验室开放基金(2011KFKT06)和中央高校基本科研业务费专项资金(65011981)资助项目 (1.南开大学 光电子薄膜器件与技术研究所光电子薄膜器件与技术天津市重点实验室, 光电信息技术科学教育部重点实验室,天津 300071; 2.河北工业大学 信息工程学院,天津 300130)


Surface morphology and light trapping properties of textured ZnO films
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    摘要:

    针对当前薄膜太阳电池对光管理的迫切需求,采 用磁控溅射及后腐蚀技术制备获 得了高性能绒 面铝掺杂氧化锌(AZO,ZnO:Al)前电极。深入分析了ZnO多晶薄膜厚度及腐蚀时间对绒面 结构及陷光特性的影响。研究 结果表明,随多晶薄膜厚度的增加,晶粒尺寸增大,腐蚀后获得的弹坑状表面结构的粒径亦 随之增大,绒 度增大;随后腐蚀时间的增加,弹坑状粒径及绒度均具有先增大而后趋于饱和的趋势。当沉 积ZnO多晶 薄膜初始厚达2μm时,获得的薄膜电阻率小于3×10-4 Ω· cm,经180s稀HCl(0.5%)腐蚀后,绒面 ZnO 的均方根粗糙度(RMS)达143nm, 400~ 1100nm平均透过率达81.4%, 在500nm处绒度为84.3%nm处绒度可达73.8%,方块电阻小于5Ω/□,满足了硅基 薄膜叠层电池对前电极的光电性能需求。

    Abstract:

    Light trapping technique plays an important role in the high-performance thin f ilm solar cells.In the present study,highly textured ZnO:Al (AZO) films are prepared by medium freq uency impulsed magnetron sputtering and wet etching technology which are influen ced by film thickness and etching time.The high-quality textured AZO surface is formed by wet etching after the films are deposited by magnetron sputtering tec hnology.The effects of film thickness and etching-time on the textured structur e and light-trapping characteristics are investigated.AZO films with different thicknesses are obtained by changing sputtering time,Precise etching time contro l leads to different textured structure with various light trapping properties.T his textured surface morphology leads to a high haze factor which provides high light trapping efficiency.In addition,the electrical propert ies of AZO films are also enhanced with higher carrier concentration and mobilit y as thickness increases.Layers with outstanding electrical (resistivity less th an 3×10-4 Ω·cm),optical (average total transmittance higher than 81% from 400nm to 1100nm),haze (84.3% and 73.8% at 500nm and 750nm respectively) and morphological (RMS higher than 143nm,after a 180s etching process) properties have been obtained,satisfying the demands of photoelectric p roperty of front contact in thin film silicon solar cells and illustrating a goo d potential application in mass production for large area expansibility.

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林小园,黄茜,张德坤,牟村,赵颖,张存善,张晓丹. ZnO多晶薄膜绒面结构及陷光特性分析[J].光电子激光,2013,(3):523~529

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  • 收稿日期:2012-08-24
  • 最后修改日期:2012-11-01
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