基于多次反射样品池的TDLAS逃逸NH3检测研究
DOI:
CSTR:
作者:
作者单位:

作者简介:

张增福(1979-),男,博士后,从事环保仪器、痕量成分光电 检测技术研究.

通讯作者:

中图分类号:

基金项目:

国家“863”计划(2012AA022602)、国家重大科学仪器专项(2012YQ 060165)资助项目 (天津大学 精密测试技术及仪器国家重点实验室,天津 300072)


Detection of escaping NH3based on TDLAS with multi-pass cells
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    时域激光吸收光谱(TDLAS)技术具有高选择性、 高准确性优点,为逃逸NH3的在线检测提供了可靠的技术手段。本文利用TDLAS 系统分别在White和Herriott 两种样品池中对浓度为(10~100)×10-6的NH3进行检测, 采集得到其二次谐波光谱,比较 了两种样品池测量结果,分析对比两种样品池的优缺点。实验显示,Herriott样品池的噪声 要大,根据光谱曲线的标准偏差得到White样品池最低检出限为1.21×10-6 ,Herriott样品池 的检测限为1.61×10-6。结果表明,Herriott样品池更适合 恶劣环境现场应用,能够满足逃逸NH3的痕量检测要求,适合在线监测。

    Abstract:

    Time-domain laser absorption spectroscopy (TDLAS) with the advantages of high selectivity and high accuracy provides a reliable means of on -line detection technology for escaping ammonia (NH3).The concentrations from 10×10-6 to 100×10-6 of NH3were detected with the TDLAS system in the two multi- pass cells of White cell and Herriott cell,and their second harmonic spectra were collected .The two kinds of cell measurement results are compared,and the advantages and disadvantages are analyzed and compared.Experiment results show that the no ise of the Herriott cell is higher than that of the White cell.According to the standar d deviation of spectral curves,the detection limit of NH3concentration is 1.21×10-6 in White cell,and is 1.61×10-6 in Herriot cell.The resu lts show that the Herriott cell is more suitable for the harsh environment,and the system can meet the requirements of trace detection of escaping ammonia,suitable for on-line monitoring.

    参考文献
    相似文献
    引证文献
引用本文

张增福,邹得宝,陈文亮,赵会娟,徐可欣.基于多次反射样品池的TDLAS逃逸NH3检测研究[J].光电子激光,2013,(12):2367~2371

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2013-04-10
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期:
  • 出版日期:
文章二维码