Yb,Er,Eu:YAP中红外激光晶体的生长与光谱特性
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孙敦陆(1972-),男,博士,研究员,博士生导师,主要从事 光电功能晶体材料生长及性能方面的研究工作.

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国家自然科学基金(91122021,4,61205173,6和50932005)资助项目 (1.合肥工业大学 化学工程学院,安徽 合肥 230009; 2.中国科学院安徽光学精密机械研 究所,安徽省光子器件与材料重点实验室,安徽 合肥 230031)


Growth and spectroscopic characterizations of the mid-infrared Yb,Er,Eu:YAP la ser crystal
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    摘要:

    用提拉法成功生长出3种不同掺Eu3+浓度的 优质Yb,Er,Eu:YAP激光晶体,并对其光谱特性进行了研究。测量 了晶体在320~3000nm波段内的吸收光谱,晶 体在978n m附近有强的吸收峰和宽的吸收带。用波长为975nm的LD连续激光和 OPO光参量脉冲激光激发分别获得了晶体的稳态和瞬态荧光光谱,采用单指数衰减拟合得 到2.7~3.0 μm激光上下能级 寿命。与单掺Er:YAP晶体的光谱参数进行了比较,对Yb3+的敏化及Eu3+的退激 活机理进行了分析。结果表明,Yb3+ 和Eu3+可分别作为Er3+的敏化剂和退激活剂,增宽978n m附近的吸收带和降低 激光下能级(4I13/2)与上能级(4I11/2)寿命的比 值(4.1,3.1和2.7);而在单掺Er:YAP晶体,下能级与上 能级寿命的比值高达10.8,不利于激光性能的提高。因 此,Yb,Er,Eu:YAP是一种更适合LD泵浦,有望实现低阈值、2.7~3.0 μm高效率激光输出的新型激光晶体。

    Abstract:

    We report the Yb,Er,Eu:YAP laser crystals with three different Eu3+ do ping concentrations grown by the Czochralski method and investigate their spectroscopic characteristics.The abso rption spectrum in the range of 320-3000nm is measured,and there is strong absorption and w ide absorption band around 978nm.The fluorescence spectrum and decay curves are measured by the excitation of 975nm LD and OPO laser,respectively.The level lifetime is obtained with single exponential decay.These parameters are compared with tho se of the single doped Er:YAP crystal and the sensitization and deactivation mechanisms are analyzed.The results indicate th at the Yb3+ and Eu3+ ions can act as sensitizer and deactivator for Er3+ ions,respectively,resulting in the wid ening of the absorption band at 978nm and decreasing of the lifetime ratio (4.1,3.1and 2.7) between the lower laser leve l (4I13/2) and upper laser level ( 4I11/2). However,the lifetime ratio of single doped Er:YAP is very high and up to 10.8, which is disadvantageous to the improvement of the laser output properties.Therefore,the new Yb,Er,Ho:YAP laser crystal is mo re suitable to be pumped by 970-980nm LD laser and the 2.7-3.0μm laser output could be realized easily with lower l aser threshold and higher laser conversion efficiency.

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谷长江,陈祥迎,孙敦陆,罗建乔,陈家康,张会丽,张庆礼,殷绍唐. Yb, Er, Eu:YAP中红外激光晶体的生长与光谱特性[J].光电子激光,2014,(3):491~495

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  • 收稿日期:2013-08-31
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