Abstract:The performance improvement of Rubrene/C70 based organic solar cells ( OSCs) with WO3as buffer layer is studied in this paper.The OSCs with the structure of ITO/WO 3/Rubrene/C70/BCP/Al were fabricated.WO3was used as anode buffer la yer,inserted between ITO and Rubrene.The performance and mechanism of the OSCs are studied by inserting WO3with different thicknesses as buffer layer.The experimental results show that the characterist ic parameters of the OSCs, including the short-circuit current(Jsc),open -circuit voltage(Voc),filling factor (FF), series resistance (Rs) and power convers ion efficiency (PCE),have a regular change with different WO3thicknesses as buffer layers.The PCE of the OSCs i s increased with the increasing thickness of WO3,when the thickness is smaller than 80nm.The PCE of the OSCs is decreased with the increasing thickness of WO3,when the thickness is larger than 80nm.T he PCE of the device is as high as 1.03% with 80nm-thick WO3while the J sc ,Voc,FF and Rs of the O SCs are 2.81mA·cm-2,0.83V,43.85% and 45.3Ω·cm2,respectively.Compared with the device without buffer layer,t he Jsc,Voc,FF and PCE of the OSCs are enhanced by 31%,137%,17% and 268%,respectively.Rs is reduced by 33%.