基于激光诱导击穿光谱技术的金属基体辅助测量研究
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(1.河北大学 质量技术监督学院,河北 保定 071000; 2.计量仪器与系统国家地方联合工 程研究中心,河北 保定 071000)

作者简介:

李红莲(1979-),女,博士,副教授,硕士生 导师,主要从事光谱检测技术及其在气体以及固体测量中的应用和可调谐光纤激光器及应用 等方面的研究.

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河北省自然科学基金重点项目(E2017201142)、河北省博士后科研项目(B2016003008)资助项目和河北省研究生创新资 助项目(CXZZSS2020013)资助项目 (1.河北大学 质量技术监督学院,河北 保定 071000; 2.计量仪器与系统国家地方联合工 程研究中心,河北 保定 071000)


Research on metal matrix-assisted measurement based on laser-induced breakdown spectroscopy
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(1.College of Quality and Technology Supervising,Hebei University,Baoding 071000,China; 2.National and local joint engineering center of measuring instrumen ts and metrology systems,Baoding 071000,China)

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    摘要:

    为了降低土壤中基体效应对激光诱导击穿光谱技 术(Laser-induced breakdown spec troscopy,LIBS)定量分析的影响,采用了Cu、Al、Zn三种金属作为基体辅助LIBS检测土壤 中的重金属元素。以Cd I 288.08 nm为特征谱线进行定量分析,得到 了三种金属基体的原子 谱线图,计算出等离子体特征参数。相比于压片条件,在三种金属基体辅助条件下的谱线强 度均有明显的增强,定标曲线拟合系数R2都在0.97以 上,且相对标准偏差RSD低于7%。实验 结果表明采用金属基体辅助LIBS检测的方法,提高了LIBS在土壤重金属检测的灵敏度,这对 土壤中重金属元素的检测具有重要意义。

    Abstract:

    In order to reduce some of the influence of the matrix effect in the soil on the quantitative analysis of laser-induced breakdown spectroscopy (LIBS ) .Three metals with high purity,Cu,Al and Zn are used as the matrix to assist t he detection of heavy metal elements in the soil by laser-induced breakdown spe c troscopy.First of all,Taking Cd I 288.08nm as the characteristic spectral line for quantitative analysis,after data fitting,the atomic spectral diagrams of t he three metal substrates are obtained,and the plasma characteristic parameters are calculated by the spectral diagrams and related parameters.It can be obtain ed from the data that compared with the tableting conditions,the spectral line intensity under the auxiliary conditions of the three metal substrates is signif icantly enhanced,the calibration curve fitting coefficient R2is all above 0.97,And the relative standard deviation (RSD) is all below 7%,the element detect ion limit has also been reduced.Finally,the experimental results show that the u se of metal matrix-assisted LIBS detection method will increase the sensitivity of LIBS in the detection of heavy metals in the soil and reduce the detection li mit,which is of great significance for the detection of heavy metals in the soi l.

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李红莲,谢红杰,吕贺帅,张仕钊,祝彦,李小亭.基于激光诱导击穿光谱技术的金属基体辅助测量研究[J].光电子激光,2021,32(2):166~172

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  • 收稿日期:2020-09-30
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  • 在线发布日期: 2021-03-11
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