高能N等离子源辅助GaN薄膜生长及其物性研究
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(浙江理工大学 理学院,浙江 杭州 310018)

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胡海争 (1995-),男,硕士,助理实验师,主要从事宽禁带半导体材料生长与光电器件方面的研究。

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O472

基金项目:

国家自然科学基金(62274148)和浙江省教育厅一般项目(23060158-F)资助项目


Studies on the growth and physical properties of GaN thin films assisted by high-energy Nplasma sources
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(School of Science, Zhejiang Sci Tech University, Hangzhou, Zhejiang 310018, China)

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    摘要:

    氮化镓 (GaN)具有宽带隙、高量子效率、优异的热稳定和抗辐射等特性,在高频、高功率电子及紫外光电器件中有着重要的作用。在本工作中,采用经济、环保的等离子增强化学气相沉积(plasma-enhanced chemical vapor deposition,PECVD)方法,通过使用高能N等离子体作为N源,在较低温度(850 ℃)下成功制备了高结晶质量的GaN薄膜,并研究了N2流量对薄膜结晶质量、生长速率和光学性能的影响。结果表明,随着N2流量的增加,反应原子的动能提高,薄膜生长速度和结晶质量得以提升。但随着N2流量进一步增加,过高的成核率会导致衬底吸附的原子无法迁移到适当的位置,薄膜沿着不同的方向上随机生长,晶体质量下降。本文制备的GaN薄膜的载流 子浓度达到2.19×1018 cm-3,迁移率达到5.17cm2·V-1·s-1,在光电子器件中展现出较强的应用潜力。

    Abstract:

    GaN with a wide band gap,high quantum efficiency,excellent thermal stability,and radiation resistance is important role in high frequency,high power electronics,and UV photoelectron devices.In this study,we present a novel approach by utilizing high-energy Nplasma as the Nsource for synthesizing the GaN films with higher crystalline quality.This process occurs at a relatively low temperature of 850 °C,utilizing the economical and eco-friendly plasma-enhanced chemical vapor deposition (PECVD) method.Furthermore,the effects of N2 flux on the crystalline quality of the films, growth rate and optical characteristics are investigated.The results reveal that an increase in N2 flux enhances both the film growth rate and crystalline quality by boosting the kinetic energy of reacting atoms.Nevertheless,a further increase in N2 flux results in excessive nucleation rate,preventing atoms adsorbed on the substrate from migrating to appropriate positions.Consequently,the films grow in random directions,leading to a decline in crystalline quality.The GaN films prepared in this study achieve a carrier concentration of 2.19×1018 cm-3 and mobility of 5.17 cm2·V-1·s-1,demonstrating significant potential for optoelectronic device applications.

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胡海争,贺怀乐,赖黎,王顺利,吴超,郭道友.高能N等离子源辅助GaN薄膜生长及其物性研究[J].光电子激光,2024,35(9):987~992

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  • 收稿日期:2024-02-01
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  • 在线发布日期: 2024-08-19
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